| 2024-04-28 17:30:00April 28, 2024 |  Villarreal vs Rayo Vallecano | 3 - 0 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2024-04-21 15:15:00April 21, 2024 | Almeria vs Villarreal | 1 - 2 | La Liga | 2023-2024 | Power Horse Stadium – Estadio de los Juegos Mediterráneos |
| 2024-04-14 17:30:00April 14, 2024 | Athletic Club vs Villarreal | 1 - 1 | La Liga | 2023-2024 | San Mamés Barria |
| 2024-04-01 20:00:00April 1, 2024 | Villarreal vs Atletico Madrid | 1 - 2 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2024-03-17 16:15:00March 17, 2024 | Villarreal vs Valencia | 1 - 0 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2024-03-14 18:45:10March 14, 2024 | Villarreal vs Marseille | 3 - 1 | UEFA Europa League | 2023-2024 | |
| 2024-03-10 20:00:00March 10, 2024 | Real Betis vs Villarreal | 2 - 3 | La Liga | 2023-2024 | Estadio Benito Villamarín |
| 2024-03-07 21:00:32March 7, 2024 | Marseille vs Villarreal | 4 - 0 | UEFA Europa League | 2023-2024 | |
| 2024-02-11 01:00:00February 11, 2024 | Alaves vs Villarreal | - | La Liga | 2023-2024 | Estadio de Mendizorroza |
| 2024-02-04 01:00:00February 4, 2024 | Villarreal vs Cadiz | - | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2024-01-28 01:00:00January 28, 2024 | Barcelona vs Villarreal | - | La Liga | 2023-2024 | Estadi Olímpic Lluís Companys |
| 2024-01-21 01:00:00January 21, 2024 | Villarreal vs Mallorca | - | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2024-01-14 01:00:00January 14, 2024 | Las Palmas vs Villarreal | - | La Liga | 2023-2024 | Estadio de Gran Canaria |
| 2024-01-02 21:30:00January 2, 2024 | Valencia vs Villarreal | 3 - 1 | La Liga | 2023-2024 | Estadio de Mestalla |
| 2023-12-20 21:30:00December 20, 2023 | Villarreal vs Celta Vigo | 3 - 2 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-12-17 21:00:00December 17, 2023 | Real Madrid vs Villarreal | 4 - 1 | La Liga | 2023-2024 | Estadio Santiago Bernabéu |
| 2023-12-14 18:45:00December 14, 2023 | Rennes vs Villarreal | 2 - 3 | UEFA Europa League | 2023-2024 | Roazhon Park |
| 2023-12-09 18:30:00December 9, 2023 | Villarreal vs Real Sociedad | 0 - 3 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-12-06 20:00:00December 6, 2023 | Villarreal vs Maccabi Haifa | 0 - 0 | UEFA Europa League | 2023-2024 | Estadio de la Cerámica |
| 2023-12-03 18:30:00December 3, 2023 | Sevilla vs Villarreal | 1 - 1 | La Liga | 2023-2024 | Estadio Ramón Sánchez Pizjuán |
| 2023-11-30 21:00:00November 30, 2023 | Villarreal vs Panathinaikos | 3 - 2 | UEFA Europa League | 2023-2024 | Estadio de la Cerámica |
| 2023-11-26 14:00:00November 26, 2023 | Villarreal vs Osasuna | 3 - 1 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-11-22 21:00:00November 22, 2023 | Zamora vs Villarreal | 1 - 1 | Copa Del Rey | 2023-2024 | Estadio Ruta de la Plata |
| 2023-11-12 20:00:00November 12, 2023 | Atletico Madrid vs Villarreal | 3 - 1 | La Liga | 2023-2024 | Estádio Cívitas Metropolitano |
| 2023-11-09 18:45:00November 9, 2023 | Maccabi Haifa vs Villarreal | 1 - 2 | UEFA Europa League | 2023-2024 | AEK Arena - George Karapatakis |
| 2023-11-05 18:30:00November 5, 2023 | Villarreal vs Athletic Club | 2 - 3 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-11-02 19:00:00November 2, 2023 | Chiclana vs Villarreal | 0 - 5 | Copa Del Rey | 2023-2024 | Estadio Municipal del Chiclana |
| 2023-10-30 21:00:00October 30, 2023 | Granada CF vs Villarreal | 2 - 3 | La Liga | 2023-2024 | Estadio Nuevo Los Cármenes |
| 2023-10-22 17:30:00October 22, 2023 | Villarreal vs Alaves | 1 - 1 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-10-08 13:00:00October 8, 2023 | Villarreal vs Las Palmas | 1 - 2 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-10-05 20:00:00October 5, 2023 | Villarreal vs Rennes | 1 - 0 | UEFA Europa League | 2023-2024 | Estadio de la Cerámica |
| 2023-09-30 13:00:00September 30, 2023 | Getafe vs Villarreal | 0 - 0 | La Liga | 2023-2024 | Estadio Coliseum |
| 2023-09-27 18:00:00September 27, 2023 | Villarreal vs Girona | 1 - 2 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-09-24 15:15:00September 24, 2023 | Rayo Vallecano vs Villarreal | 1 - 1 | La Liga | 2023-2024 | Estadio de Vallecas |
| 2023-09-21 17:45:00September 21, 2023 | Panathinaikos vs Villarreal | 2 - 0 | UEFA Europa League | 2023-2024 | Olympiako Stadio Spyros Louis |
| 2023-09-17 15:15:00September 17, 2023 | Villarreal vs Almeria | 2 - 1 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-09-01 18:30:00September 1, 2023 | Cadiz vs Villarreal | 3 - 1 | La Liga | 2023-2024 | Estadio Nuevo Mirandilla |
| 2023-08-27 16:30:11August 27, 2023 | Villarreal vs Barcelona | 3 - 4 | La Liga | 2023-2024 | |
| 2023-08-18 18:30:00August 18, 2023 | Mallorca vs Villarreal | 0 - 1 | La Liga | 2023-2024 | Estadi Mallorca Son Moix |
| 2023-08-13 18:30:00August 13, 2023 | Villarreal vs Real Betis | 1 - 2 | La Liga | 2023-2024 | Estadio de la Cerámica |
| 2023-06-04 17:30:00June 4, 2023 | Villarreal CF vs Atletico Madrid | 2 - 2 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-05-28 18:00:00May 28, 2023 | Rayo Vallecano vs Villarreal CF | 2 - 1 | La Liga | 2022/2023 | Estadio de Vallecas |
| 2023-05-24 18:30:00May 24, 2023 | Villarreal CF vs Cadiz CF | 2 - 0 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-05-20 13:00:00May 20, 2023 | Girona vs Villarreal CF | 1 - 2 | La Liga | 2022/2023 | Municipal de Montilivi |
| 2023-05-13 17:30:00May 13, 2023 | Villarreal CF vs Athletic Club | 5 - 1 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-05-03 18:30:00May 3, 2023 | Valencia vs Villarreal CF | 1 - 1 | La Liga | 2022/2023 | Mestalla |
| 2023-04-30 02:00:00April 30, 2023 | Villarreal CF vs Celta Vigo | 3 - 1 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-04-26 02:00:00April 26, 2023 | Villarreal CF vs Espanyol | 4 - 2 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-04-23 02:00:00April 23, 2023 | Sevilla FC vs Villarreal CF | 2 - 1 | La Liga | 2022/2023 | Ramón Sánchez-Pizjuán |
| 2023-04-16 02:00:00April 16, 2023 | Villarreal CF vs Real Valladolid | 1 - 2 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-04-08 19:00:00April 8, 2023 | Real Madrid vs Villarreal CF | 2 - 3 | La Liga | 2022/2023 | Santiago Bernabéu |
| 2023-04-02 16:30:00April 2, 2023 | Villarreal CF vs Real Sociedad | 2 - 0 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-03-19 16:15:00March 19, 2023 | Osasuna vs Villarreal CF | 0 - 3 | La Liga | 2022/2023 | El Sadar |
| 2023-03-12 18:30:00March 12, 2023 | Villarreal CF vs Real Betis | 1 - 1 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-03-04 16:15:00March 4, 2023 | UD Almeria vs Villarreal CF | 0 - 2 | La Liga | 2022/2023 | Estadio de los Juegos Mediterráneos |
| 2023-02-27 21:00:00February 27, 2023 | Villarreal CF vs Getafe CF | 2 - 1 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-02-18 18:30:00February 18, 2023 | Real Mallorca vs Villarreal CF | 4 - 2 | La Liga | 2022/2023 | Visit Mallorca Estadi |
| 2023-02-12 21:00:00February 12, 2023 | Villarreal CF vs Barcelona | 0 - 1 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-02-04 16:15:00February 4, 2023 | Elche CF vs Villarreal CF | 3 - 1 | La Liga | 2022/2023 | Martínez Valero |
| 2023-01-30 21:00:00January 30, 2023 | Villarreal CF vs Rayo Vallecano | 0 - 1 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-01-22 14:00:00January 22, 2023 | Villarreal CF vs Girona | 1 - 0 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-01-19 21:00:32January 19, 2023 | Villarreal vs Real Madrid | 2 - 3 | Copa Del Rey | 2022/2023 | |
| 2023-01-13 21:00:00January 13, 2023 | Celta Vigo vs Villarreal CF | 1 - 1 | La Liga | 2022/2023 | Balaídos |
| 2023-01-07 16:15:00January 7, 2023 | Villarreal CF vs Real Madrid | 2 - 1 | La Liga | 2022/2023 | Estadio de la Cerámica |
| 2023-01-03 19:00:00January 3, 2023 | FC Cartagena vs Villarreal CF | 1 - 5 | Copa Del Rey | 2022/2023 | |
| 2022-12-31 16:15:00December 31, 2022 | Villarreal CF vs Valencia | 2 - 1 | La Liga | 2022/2023 | Ciutat de Valencia |
| 2022-11-09 20:00:00November 9, 2022 | Espanyol vs Villarreal CF | 0 - 1 | La Liga | 2022/2023 | RCDE Stadium |
| 2022-11-06 18:30:00November 6, 2022 | Villarreal CF vs Real Mallorca | 0 - 2 | La Liga | 2022/2023 | Ciutat de Valencia |
| 2022-10-30 02:00:00October 30, 2022 | Athletic Club vs Villarreal CF | 1 - 0 | La Liga | 2022/2023 | San Mamés |
| 2022-10-23 17:30:00October 23, 2022 | Villarreal CF vs UD Almeria | 2 - 1 | La Liga | 2022/2023 | Ciutat de Valencia |
| 2022-10-20 20:00:00October 20, 2022 | Barcelona vs Villarreal CF | 3 - 0 | La Liga | 2022/2023 | Spotify Camp Nou |
| 2022-10-17 20:00:00October 17, 2022 | Villarreal CF vs Osasuna | 2 - 0 | La Liga | 2022/2023 | Ciutat de Valencia |
| 2022-10-09 17:30:00October 9, 2022 | Real Sociedad vs Villarreal CF | 1 - 0 | La Liga | 2022/2023 | Reale Arena |
| 2022-10-01 13:00:00October 1, 2022 | Cadiz CF vs Villarreal CF | 0 - 0 | La Liga | 2022/2023 | Nuevo Mirandilla |
| 2022-09-18 15:15:00September 18, 2022 | Villarreal CF vs Sevilla FC | 1 - 1 | La Liga | 2022/2023 | Ciutat de Valencia |
| 2022-09-11 20:00:00September 11, 2022 | Real Betis vs Villarreal CF | 1 - 0 | La Liga | 2022/2023 | Benito Villamarín |
| 2022-09-04 17:30:00September 4, 2022 | Villarreal CF vs Elche CF | 4 - 0 | La Liga | 2022/2023 | Ciutat de Valencia |
| 2022-08-28 16:30:00August 28, 2022 | Getafe CF vs Villarreal CF | 0 - 0 | La Liga | 2022/2023 | Coliseum Alfonso Pérez |
| 2022-08-21 18:30:00August 21, 2022 | Atletico Madrid vs Villarreal CF | 0 - 2 | La Liga | 2022/2023 | Wanda Metropolitano |
| 2022-08-13 18:00:00August 13, 2022 | Real Valladolid vs Villarreal CF | 0 - 3 | La Liga | 2022/2023 | |
| 2022-07-30 15:00:52July 30, 2022 | Southampton vs Villarreal | 1 - 2 | | | |
| 2022-07-24 18:00:30July 24, 2022 | Stade de Reims vs Villarreal | 0 - 1 | | | |
| 2022-07-22 18:00:38July 22, 2022 | Borussia Dortmund vs Villarreal | 0 - 2 | | | |
| 2022-07-16 18:00:01July 16, 2022 | PSV Eindhoven vs Villarreal | 1 - 2 | | | |
| 2022-07-14 21:00:12July 14, 2022 | Sporting CP vs Villarreal | 1 - 1 | | | |
| 2022-05-22 21:00:00May 22, 2022 | Barcelona vs Villarreal | 0 - 2 | La Liga | 2021-2022 | |
| 2022-05-15 18:30:00May 15, 2022 | Villarreal vs Real Sociedad | 1 - 2 | La Liga | 2021-2022 | |
| 2022-05-12 19:00:00May 12, 2022 | Vallecano vs Villarreal | 1 - 5 | La Liga | 2021-2022 | |
| 2022-05-08 16:15:00May 8, 2022 | Villarreal vs Sevilla | 1 - 1 | La Liga | 2021-2022 | |
| 2022-05-03 20:00:53May 3, 2022 | Villarreal vs Liverpool | 2 - 3 | Champions League | 2021-2022 | |
| 2022-04-30 13:00:00April 30, 2022 | Alaves vs Villarreal | 2 - 1 | La Liga | 2021-2022 | |
| 2022-04-27 20:00:51April 27, 2022 | Liverpool vs Villarreal | 2 - 0 | Champions League | 2021-2022 | |
| 2022-04-19 20:30:00April 19, 2022 | Villarreal vs Valencia | 2 - 0 | La Liga | 2021-2022 | |
| 2022-04-16 20:00:00April 16, 2022 | Getafe vs Villarreal | 1 - 2 | La Liga | 2021-2022 | |
| 2022-04-12 20:00:51April 12, 2022 | Bayern München vs Villarreal | 1 - 1 | Champions League | 2021-2022 | |
| 2022-04-09 17:30:00April 9, 2022 | Villarreal vs Athletic Club | 1 - 1 | La Liga | 2021-2022 | |
| 2022-04-06 20:00:42April 6, 2022 | Villarreal vs Bayern Munchen | 1 - 0 | Champions League | 2021-2022 | |
| 2022-04-02 15:15:00April 2, 2022 | Levante vs Villarreal | 2 - 0 | La Liga | 2021-2022 | |
| 2022-03-20 16:15:00March 20, 2022 | Cadiz vs Villarreal | 1 - 0 | La Liga | 2021-2022 | |
| 2022-03-16 21:00:00March 16, 2022 | Juventus vs Villarreal | 0 - 3 | Champions League | 2021-2022 | |
| 2022-03-12 18:30:00March 12, 2022 | Villarreal vs Celta | 1 - 0 | La Liga | 2021-2022 | |
| 2022-03-05 14:00:00March 5, 2022 | Osasuna vs Villarreal | 1 - 0 | La Liga | 2021-2022 | |
| 2022-02-27 14:00:00February 27, 2022 | Villarreal vs Espanyol | 5 - 1 | La Liga | 2021-2022 | |
| 2022-02-22 21:00:00February 22, 2022 | Villarreal vs Juventus | 1 - 1 | Champions League | 2021-2022 | |
| 2022-02-19 02:00:00February 19, 2022 | Granada vs Villarreal | 1 - 4 | La Liga | 2021-2022 | |
| 2022-02-12 04:15:00February 12, 2022 | Villarreal vs Real Madrid | 0 - 0 | La Liga | 2021-2022 | |
| 2022-02-06 06:30:00February 6, 2022 | Real Betis vs Villarreal | 0 - 2 | La Liga | 2021-2022 | |
| 2022-01-22 16:15:00January 22, 2022 | Villarreal vs Mallorca | 3 - 0 | La Liga | 2021-2022 | |
| 2022-01-16 14:00:00January 16, 2022 | Elche vs Villarreal | 1 - 0 | La Liga | 2021-2022 | |
| 2022-01-09 21:00:00January 9, 2022 | Villarreal vs Atletico Madrid | 2 - 2 | La Liga | 2021-2022 | |
| 2022-01-06 18:00:00January 6, 2022 | Sporting Gijon vs Villarreal | 2 - 1 | Copa Del Rey | 2021-2022 | |
| 2022-01-03 19:00:00January 3, 2022 | Villarreal vs Levante | 5 - 0 | La Liga | 2021-2022 | |
| 2021-12-21 19:00:00December 21, 2021 | Villarreal vs Alaves | 5 - 2 | La Liga | 2021-2022 | |
| 2021-12-18 16:15:00December 18, 2021 | Real Sociedad vs Villarreal | 1 - 3 | La Liga | 2021-2022 | |
| 2021-12-12 14:00:00December 12, 2021 | Villarreal vs Vallecano | 2 - 0 | La Liga | 2021-2022 | |
| 2021-12-09 19:00:00December 9, 2021 | Atalanta vs Villarreal | 2 - 3 | Champions League | 2021-2022 | |
| 2021-12-04 14:00:00December 4, 2021 | Sevilla vs Villarreal | 1 - 0 | La Liga | 2021-2022 | |
| 2021-11-27 21:00:00November 27, 2021 | Villarreal vs Barcelona | 1 - 3 | La Liga | 2021-2022 | |
| 2021-11-23 18:45:00November 23, 2021 | Villarreal vs Man United | 0 - 2 | Champions League | 2021-2022 | |
| 2021-11-20 14:00:00November 20, 2021 | Celta vs Villarreal | 1 - 1 | La Liga | 2021-2022 | |
| 2021-11-07 14:00:00November 7, 2021 | Villarreal vs Getafe | 1 - 0 | La Liga | 2021-2022 | |
| 2021-11-02 09:00:00November 2, 2021 | Villarreal vs Young Boys | 2 - 0 | Champions League | 2021-2022 | |
| 2021-10-30 17:30:00October 30, 2021 | Valencia vs Villarreal | 2 - 0 | La Liga | 2021-2022 | |
| 2021-10-26 20:30:00October 26, 2021 | Villarreal vs Cadiz | 3 - 3 | La Liga | 2021-2022 | |
| 2021-10-23 20:00:00October 23, 2021 | Athletic Club vs Villarreal | 2 - 1 | La Liga | 2021-2022 | |
| 2021-10-20 20:00:00October 20, 2021 | Young Boys vs Villarreal | 1 - 4 | Champions League | 2021-2022 | |
| 2021-10-17 17:30:00October 17, 2021 | Villarreal vs Osasuna | 1 - 2 | La Liga | 2021-2022 | |
| 2021-10-03 17:30:00October 3, 2021 | Villarreal vs Real Betis | 2 - 0 | La Liga | 2021-2022 | |
| 2021-09-29 20:00:54September 29, 2021 | Man United vs Villarreal | 2 - 1 | Champions League | 2021-2022 | |
| 2021-09-25 20:00:00September 25, 2021 | Real Madrid vs Villarreal | 0 - 0 | La Liga | 2021-2022 | |
| 2021-09-22 21:00:00September 22, 2021 | Villarreal vs Elche | 4 - 1 | La Liga | 2021-2022 | |
| 2021-09-19 13:00:00September 19, 2021 | Mallorca vs Villarreal | 0 - 0 | La Liga | 2021-2022 | |
| 2021-09-14 20:00:00September 14, 2021 | Villarreal vs Atalanta | 2 - 2 | Champions League | 2021-2022 | |
| 2021-08-29 21:00:00August 29, 2021 | Atletico Madrid vs Villarreal | 2 - 2 | La Liga | 2021-2022 | |
| 2021-08-21 18:30:00August 21, 2021 | Espanyol vs Villarreal | 0 - 0 | La Liga | 2021-2022 | |
| 2021-08-16 19:00:00August 16, 2021 | Villarreal vs Granada | 0 - 0 | La Liga | 2021-2022 | |
